English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/171034
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE
Exportar a otros formatos:


From diiodo Tröger's bases towards halogen-bonded porous organic crystalline materials

AuthorsGonzález, Lucía; Graus, Sara; Tejedor, Rosa M.; López, Pilar; Elguero, José ; Serrano, José Luis; Uriel, Santiago
Issue Date2018
PublisherRoyal Society of Chemistry (UK)
CitationCrystEngComm 20(23): 3167-3170 (2018)
AbstractRacemic 2,8-diiodo-6H,12H-5,11-methanodibenzodiazocine (rac-1) and racemic 2,8-diiodoethynyl-6H,12H-5,11-methano-dibenzodiazocine (rac-2) proved to be self-complementary tectons that are particularly suitable for the formation of porous supramolecular structures by halogen bonding. Crystals structures of clathrate rac-1·CHCl and rac-2 show channels, which represent 20% of the cell volume, and these are stabilized by strong C-I⋯N and C-I⋯π halogen bonds.
Publisher version (URL)http://dx.doi.org/10.1039/c8ce00557e
Identifiersdoi: 10.1039/c8ce00557e
issn: 1466-8033
Appears in Collections:(IQM) Artículos
(ICMA) Artículos
Files in This Item:
File Description SizeFormat 
accesoRestringido.pdf15,38 kBAdobe PDFThumbnail
Show full item record
Review this work

Related articles:

WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.