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Title

On-surface chemistry: cyclodehydrogenation of PAH catalyzed by metal surfaces

AuthorsPalacio, Irene; Pinardi, Anna Lisa ; Otero, Gonzalo ; Martínez, José I. ; López, María Francisca ; Méndez, Javier ; Martín-Gago, José A.
Issue DateAug-2014
CitationFuerzas y Túnel (2014)
AbstractIn this work, we show that the strength of the PAH-substrate interaction rules the competitive reaction pathways (cyclodehydrogenation versus dehydrogenative polymerisation). Starting from the same molecular precursor (C57H33N3 or C40H24N2 (DiPy[5]DBH) and controlling its diffusion by the nature of the supporting surface (Au(111) or Pt(111)), temperature-triggered dehydrogenation takes place to provide molecular or polymeric structures of variable dimensionality2-3.
DescriptionTrabajo presentado en la conferencia Fuerzas y Túnel (FyT2014), celebrada en San Sebastián del 27 al 29 de agosto de 2014.
URIhttp://hdl.handle.net/10261/169758
Appears in Collections:(ICMM) Comunicaciones congresos
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