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Title

Fragmentation of alkoxy radicals: Tandem β-fragmentation-cycloperoxyiodination reaction

AuthorsBoto, Alicia CSIC ORCID ; Betancor, Carmen; Prangé, Thierry; Suárez, Ernesto CSIC ORCID
Issue Date27-Oct-1992
PublisherElsevier
CitationTetrahedron Letters 33(44): 6687-6690 (1992)
AbstractA new tandem β-fragmentation-cycloperoxyiodination reaction is observed when a homoallylic alcohol is irradiated with visible light in the presence of (diacetoxyiodo)benzene and iodine under an atmosphere of oxygen. A synthetically interesting epidioxyiodide medium-sized ketone is obtained by this method.
Description4 pages, 1 figure, 1 table, 2 schemes.
Publisher version (URL)http://dx.doi.org/10.1016/S0040-4039(00)61020-1
URIhttp://hdl.handle.net/10261/16969
DOI10.1016/S0040-4039(00)61020-1
ISSN0040-4039
Appears in Collections:(IPNA) Artículos

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