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Organoselenium reagents in the tandem β-fragmentation-cyclization of carbohydrate anomeric alkoxy radicals

AuthorsDorta, Rosa L. ; Francisco, Cosme G. ; Suárez, Ernesto
Issue Date28-Mar-1994
CitationTetrahedron Letters 35(13): 2049-2052 (1994)
AbstractCarbohydrates possessing a suitably positioned hydroxyl group in the presence of organoselenium reagents and iodine under an argon atmosphere undergo intramolecular β-fragmentation-cyclization reaction to give aldofuranose and aldopyranose forms of carbohydrates, specifically.
Description4 pages, 1 table, 1 scheme.
Publisher version (URL)http://dx.doi.org/10.1016/S0040-4039(00)73046-2
Appears in Collections:(IPNA) Artículos
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