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| Title: | A new sequential alkoxy radical fragmentation of δ-hydroxyketones |
Authors: | Boto, Alicia CSIC ORCID ; Hernández, Rosendo CSIC; Suárez, Ernesto CSIC ORCID | Issue Date: | 18-Apr-1994 | Publisher: | Elsevier | Citation: | Tetrahedron Letters 35(16): 2597-2600 (1994) | Abstract: | The alkoxy radicals formed by the reaction of steroidal cyclic hydroxyketones (1) and (2) with (diacetoxyiodo)benzene and iodine or mercuric oxide and iodine under oxygen atmosphere and irradiation with visible light undergo a new quintuple sequence β-fragmentation-peroxidation-radical reduction-radical cyclization-β-fragmentation reaction before being trapped by an atom of iodine. | Description: | 4 pages, 1 table, 2 schemes. | Publisher version (URL): | http://dx.doi.org/10.1016/S0040-4039(00)77181-4 | URI: | http://hdl.handle.net/10261/16966 | DOI: | 10.1016/S0040-4039(00)77181-4 | ISSN: | 0040-4039 |
| Appears in Collections: | (IPNA) Artículos |
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