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Title

A new sequential alkoxy radical fragmentation of δ-hydroxyketones

AuthorsBoto, Alicia CSIC ORCID ; Hernández, Rosendo CSIC; Suárez, Ernesto CSIC ORCID
Issue Date18-Apr-1994
PublisherElsevier
CitationTetrahedron Letters 35(16): 2597-2600 (1994)
AbstractThe alkoxy radicals formed by the reaction of steroidal cyclic hydroxyketones (1) and (2) with (diacetoxyiodo)benzene and iodine or mercuric oxide and iodine under oxygen atmosphere and irradiation with visible light undergo a new quintuple sequence β-fragmentation-peroxidation-radical reduction-radical cyclization-β-fragmentation reaction before being trapped by an atom of iodine.
Description4 pages, 1 table, 2 schemes.
Publisher version (URL)http://dx.doi.org/10.1016/S0040-4039(00)77181-4
URIhttp://hdl.handle.net/10261/16966
DOI10.1016/S0040-4039(00)77181-4
ISSN0040-4039
Appears in Collections:(IPNA) Artículos

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