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A selenurane derivative promotes β-fragmentation of carbinolamides leading to cyclic imides

AuthorsDorta, Rosa L. ; Francisco, Cosme G. ; Suárez, Ernesto
Issue Date14-Feb-1994
CitationTetrahedron Letters 35(7): 1083-1086 (1994)
AbstractThe alkoxy radical intermediates generated by reaction of carbinolamides with diphenylselenium hydroxyacetate (1) in the presence of iodine and under irradiation with visible light undergo β-fragmentation to afford 3,4-substituted cyclic imides in good yields.
Description4 pages, 1 table, 2 schemes.
Publisher version (URL)http://dx.doi.org/10.1016/S0040-4039(00)79971-0
Appears in Collections:(IPNA) Artículos
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