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dc.contributor.author | Moreno, Juan José | - |
dc.contributor.author | Espada, María F. | - |
dc.contributor.author | Krüger, Eric | - |
dc.contributor.author | López-Serrano, Joaquín | - |
dc.contributor.author | Campos, Jesús | - |
dc.contributor.author | Carmona, Ernesto | - |
dc.date.accessioned | 2018-09-12T08:25:01Z | - |
dc.date.available | 2018-09-12T08:25:01Z | - |
dc.date.issued | 2018 | - |
dc.identifier | doi: 10.1002/ejic.201800169 | - |
dc.identifier | issn: 1099-0682 | - |
dc.identifier.citation | European Journal of Inorganic Chemistry 2018: 2309- 2321 (2018) | - |
dc.identifier.uri | http://hdl.handle.net/10261/169575 | - |
dc.description.abstract | The synthesis of a series of cationic rhodium(I) and iridium(I) compounds stabilized by sterically demanding phosphanes that contain a terphenyl substituent PMeAr′ (Ar′ = 2,6-diarylphenyl) is described. Salt metathesis of metal precursors [MCl(COD)(PMeAr′)] (M = Rh, Ir; COD = cyclooctadiene) with NaBAr {BAr = B[3,5-CH(CF)]} resulted in a series of cationic complexes in which the loss of the chlorido ligand is compensated by the appearance of relatively weak π interactions with one of the flanking aryl rings of the terphenyl substituent. The same experiments carried out with carbonyl complexes [MCl(CO)(PMeAr′)] led to the corresponding cationic carbonyl complexes, the CO-induced rearrangement reactivity of which was investigated, both experimentally and computationally. The differences in reactivity between rhodium and iridium complexes and as a result of varying the sterics of terphenyl phosphanes are discussed. | - |
dc.publisher | Wiley-Blackwell | - |
dc.relation.isversionof | Postprint | - |
dc.rights | openAccess | en_EN |
dc.title | Ligand Rearrangement and Hemilability in Rhodium(I) and Iridium(I) Complexes Bearing Terphenyl Phosphanes | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1002/ejic.201800169 | - |
dc.embargo.terms | 2019-03-25 | - |
dc.date.updated | 2018-09-12T08:25:01Z | - |
dc.description.version | Peer Reviewed | - |
dc.language.rfc3066 | eng | - |
dc.relation.csic | Sí | - |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | With Fulltext | - |
item.cerifentitytype | Publications | - |
item.openairetype | artículo | - |
item.grantfulltext | open | - |
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EurJIC_Postprint.pdf | 1,3 MB | Adobe PDF | Visualizar/Abrir |
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