English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/169575
Share/Impact:
Statistics
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:
DC FieldValueLanguage
dc.contributor.authorMoreno, Juan José-
dc.contributor.authorEspada, María F.-
dc.contributor.authorKrüger, Eric-
dc.contributor.authorLópez-Serrano, Joaquín-
dc.contributor.authorCampos, Jesús-
dc.contributor.authorCarmona, Ernesto-
dc.date.accessioned2018-09-12T08:25:01Z-
dc.date.available2018-09-12T08:25:01Z-
dc.date.issued2018-
dc.identifierdoi: 10.1002/ejic.201800169-
dc.identifierissn: 1099-0682-
dc.identifier.citationEuropean Journal of Inorganic Chemistry 2018: 2309- 2321 (2018)-
dc.identifier.urihttp://hdl.handle.net/10261/169575-
dc.description.abstractThe synthesis of a series of cationic rhodium(I) and iridium(I) compounds stabilized by sterically demanding phosphanes that contain a terphenyl substituent PMeAr′ (Ar′ = 2,6-diarylphenyl) is described. Salt metathesis of metal precursors [MCl(COD)(PMeAr′)] (M = Rh, Ir; COD = cyclooctadiene) with NaBAr {BAr = B[3,5-CH(CF)]} resulted in a series of cationic complexes in which the loss of the chlorido ligand is compensated by the appearance of relatively weak π interactions with one of the flanking aryl rings of the terphenyl substituent. The same experiments carried out with carbonyl complexes [MCl(CO)(PMeAr′)] led to the corresponding cationic carbonyl complexes, the CO-induced rearrangement reactivity of which was investigated, both experimentally and computationally. The differences in reactivity between rhodium and iridium complexes and as a result of varying the sterics of terphenyl phosphanes are discussed.-
dc.publisherWiley-Blackwell-
dc.relation.isversionofPostprint-
dc.rightsopenAccessen_EN
dc.titleLigand Rearrangement and Hemilability in Rhodium(I) and Iridium(I) Complexes Bearing Terphenyl Phosphanes-
dc.typeArtículo-
dc.embargo.terms2019-03-25-
dc.date.updated2018-09-12T08:25:01Z-
dc.description.versionPeer Reviewed-
dc.language.rfc3066eng-
dc.relation.csic-
Appears in Collections:(IIQ) Artículos
Files in This Item:
File Description SizeFormat 
EurJIC_Postprint.pdf1,3 MBAdobe PDFThumbnail
View/Open
Show simple item record
 

Related articles:


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.