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Título

Lipase-Catalyzed Synthesis of Fatty Acid Esters of Trisaccharides

AutorGonzález-Alfonso, José L.; Casas-Godoy, Leticia; Arrizón, Javier; Arrieta-Baez, Daniel; Ballesteros Olmo, Antonio ; Sandoval, Georgina ; Plou Gasca, Francisco José
Palabras claveLipases
Acylation
Sugar esters
Transesterification
Regioselectivity
Surfactants
Maltotriose
1-Kestose
Fecha de publicación2018
EditorHumana Press
CitaciónLipases and Phospholipases 15: 287-296 (2018)
SerieMethods in Molecular Biology
1835
ResumenCarbohydrate fatty acid esters have a broad spectrum of applications in the food, cosmetic, and pharmaceutical industries. The enzyme-catalyzed acylation is significantly more selective than the chemical process and is carried out at milder conditions. Compared with mono- and disaccharides, the acylation of trisaccharides has been less studied. However, trisaccharide esters display notable bioactive properties, probably due to the higher hydrophilicity of the sugar head group. In this chapter, we describe the acylation of two trisaccharides, maltotriose and 1-kestose, catalyzed by different immobilized lipases, using vinyl esters as acyl donors. To illustrate the potential of such compounds, the antitumor activity of 6″-O-palmitoyl-maltotriose is shown.
DescripciónFirst Online: 15 August 2018.-- Sandoval G. (eds).
Versión del editorhttps://doi.org/10.1007/978-1-4939-8672-9_15
URIhttp://hdl.handle.net/10261/169516
DOI10.1007/978-1-4939-8672-9_15
ISBN978-1-4939-8672-9 (online)
ISSN978-1-4939-8671-2 (print)
1064-3745
E-ISSN1940-6029
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