Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/168009
Share/Export:
logo share SHARE logo core CORE BASE
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE
Title

Densely Packed Perylene Layers on the Rutile TiO2(110)-(1 × 1) Surface

AuthorsOtero, Gonzalo CSIC ORCID; Martínez, José I. CSIC ORCID ; Lovat, Giacomo; Lanzilotto, Valeria; Méndez, Javier CSIC ORCID; López, María Francisca ; Floreano, Luca; Martín-Gago, José A. CSIC ORCID
Issue Date20-Mar-2015
PublisherAmerican Chemical Society
CitationJournal of Physical Chemistry C 119(14): 7809-7816 (2015)
AbstractWe have studied the interaction of perylene, a prototypical organic molecule, on the TiO2(110)-(1 × 1) surface at different surface coverages by an adequate combination of ultrahigh vacuum STM and UPS techniques, together with accurate “many-body” corrected ab initio calculations. We show that the molecular coupling and adsorption configuration strongly depend on the coverage. At the submonolayer coverage, the interaction is dominated by the van der Waals substrate attraction, which keeps the molecules in the troughs between adjacent oxygen rows. At this low-coverage regime no additional interaction is detected among the molecules, which rather behave like a 2D gas. When the coverage approaches the saturation of the first layer, a side-to-side molecular attraction sets in, which is shown to be mediated by a lateral intermolecular hybridization.
Publisher version (URL)http://dx.doi.org/10.1021/acs.jpcc.5b00851
URIhttp://hdl.handle.net/10261/168009
DOI10.1021/acs.jpcc.5b00851
ISSN1932-7447
E-ISSN1932-7455
Appears in Collections:(ICMM) Artículos

Files in This Item:
File Description SizeFormat
Densely-packed-perylene-2015.pdf1,05 MBAdobe PDFThumbnail
View/Open
Show full item record
Review this work

Google ScholarTM

Check

Altmetric

Dimensions


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.