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Structural dynamics effects on the ultrafast chemical bond cleavage of a photodissociation reaction

AutorCorrales, M.E.; Loriot, V. ; Corrales, M.E; Balerdi, G.; González-Vázquez, J. ; de Nalda, R. ; Bañares, L.; Zewail, A.H.
Fecha de publicación2014
EditorRoyal Society of Chemistry (Great Britain)
CitaciónPhysical Chemistry Chemical Physics 16: 8812- 8818 (2014)
ResumenThe correlation between chemical structure and dynamics has been explored in a series of molecules with increasing structural complexity in order to investigate its influence on bond cleavage reaction times in a photodissociation event. Femtosecond time-resolved velocity map imaging spectroscopy reveals specificity of the ultrafast carbon-iodine (C-I) bond breakage for a series of linear (unbranched) and branched alkyl iodides, due to the interplay between the pure reaction coordinate and the rest of the degrees of freedom associated with the molecular structure details. Full-dimension time-resolved dynamics calculations support the experimental evidence and provide insight into the structure-dynamics relationship to understand structural control on time-resolved reactivity. This journal is © the Partner Organisations 2014.
URIhttp://hdl.handle.net/10261/167835
Identificadoresdoi: 10.1039/c3cp54677b
issn: 1463-9076
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