English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/167835
Share/Impact:
Statistics
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE
Exportar a otros formatos:

Title

Structural dynamics effects on the ultrafast chemical bond cleavage of a photodissociation reaction

AuthorsCorrales, M.E.; Loriot, V. ; Corrales, M.E; Balerdi, G.; González-Vázquez, J. ; de Nalda, R. ; Bañares, L.; Zewail, A.H.
Issue Date2014
PublisherRoyal Society of Chemistry (UK)
CitationPhysical Chemistry Chemical Physics 16: 8812- 8818 (2014)
AbstractThe correlation between chemical structure and dynamics has been explored in a series of molecules with increasing structural complexity in order to investigate its influence on bond cleavage reaction times in a photodissociation event. Femtosecond time-resolved velocity map imaging spectroscopy reveals specificity of the ultrafast carbon-iodine (C-I) bond breakage for a series of linear (unbranched) and branched alkyl iodides, due to the interplay between the pure reaction coordinate and the rest of the degrees of freedom associated with the molecular structure details. Full-dimension time-resolved dynamics calculations support the experimental evidence and provide insight into the structure-dynamics relationship to understand structural control on time-resolved reactivity. This journal is © the Partner Organisations 2014.
URIhttp://hdl.handle.net/10261/167835
DOIhttp://dx.doi.org/10.1039/c3cp54677b
Identifiersdoi: 10.1039/c3cp54677b
issn: 1463-9076
Appears in Collections:(IQFR) Artículos
Files in This Item:
File Description SizeFormat 
accesoRestringido.pdf15,38 kBAdobe PDFThumbnail
View/Open
Show full item record
Review this work
 


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.