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http://hdl.handle.net/10261/16766
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | González Martín, Concepción C. | en_US |
dc.contributor.author | León, Elisa I. | en_US |
dc.contributor.author | Riesco-Fagundo, Concepción | en_US |
dc.contributor.author | Suárez, Ernesto | en_US |
dc.date.accessioned | 2009-09-09T07:25:08Z | - |
dc.date.available | 2009-09-09T07:25:08Z | - |
dc.date.issued | 2003-07-19 | en_US |
dc.identifier.citation | Tetrahedron Letters 44(33): 6347-6350 (2003) | en_US |
dc.identifier.issn | 0040-4039 | - |
dc.identifier.uri | http://hdl.handle.net/10261/16766 | - |
dc.description | 4 pages, 2 tables.-- Printed version published Aug 11, 2003. | - |
dc.description.abstract | The reaction of 1,2-halohydrins derived from easily available carbohydrates with (diacetoxyiodo)benzene (DIB) in the presence of bromine is a mild procedure for the synthesis of 1-deoxy-1-halo-1-bromo-alditols with one carbon less than the original carbohydrate. The reaction goes through β-fragmentation of the intermediate anomeric alkoxyl radicals. These 1-halo-1-bromo polyhydroxy compounds may be valuable synthetic intermediates in organic synthesis. | - |
dc.description.sponsorship | This work was supported by the Investigation Programmes no. BQU2000-0650 and BQU2001-1665 of the Dirección General de Investigación Cientı́fica y Técnica, Spain. C.R.-F. thanks the Dirección General de Universidades e Investigación del Gobierno de Canarias for a fellowship. | - |
dc.format.extent | 2373 bytes | - |
dc.format.extent | 160132 bytes | - |
dc.format.mimetype | text/plain | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | en_US |
dc.publisher | Elsevier | - |
dc.rights | closedAccess | en_US |
dc.title | Fragmentation of carbohydrate anomeric alkoxy radicals: a new synthesis of chiral 1-halo-1-bromo compounds | en_US |
dc.type | artículo | en_US |
dc.identifier.doi | 10.1016/S0040-4039(03)01399-6 | - |
dc.relation.publisherversion | http://dx.doi.org/10.1016/S0040-4039(03)01399-6 | - |
dc.contributor.funder | Dirección General de Investigación Científica y Técnica, DGICT (España) | - |
dc.contributor.funder | Gobierno de Canarias | - |
dc.identifier.funder | http://dx.doi.org/10.13039/501100008737 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.fulltext | No Fulltext | - |
item.languageiso639-1 | en | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.openairetype | artículo | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | none | - |
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