Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/16764COMPARTIR / EXPORTAR:
 SHARE
 CORE
BASE
|
|
| Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
| Título: | Fragmentation of carbohydrate anomeric alkoxyl radicals: a new synthesis of 1,1-difluoro-1-iodo alditols |
Autor: | Francisco, Cosme G. CSIC; González Martín, Concepción C. CSIC ORCID ; Rodríguez Paz, Nieves CSIC ; Suárez, Ernesto CSIC ORCID | Fecha de publicación: | 4-oct-2003 | Editor: | American Chemical Society | Citación: | Organic Letters 5(22): 4171-4173 (2003) | Resumen: | The β-fragmentation of 2,2-difluoro-saccharide anomeric alkoxyl radicals, generated under oxidative condition by treatment of the respective alcohols with (diacetoxyiodo)benzene (DIB) and iodine, afforded 1,1-difluoro-1-iodo alditols in high yield. The reactivity of the fluorinated radical generated by rupture of the C−I bond has been preliminarily assessed by reductive deiodination with tributyltin hydride/AIBN and intermolecular allylation using the Keck reaction. | Descripción: | 3 pages, 1 table, 2 schemes.-- PMID: 14572277 [PubMed].-- Printed version published Oct 30, 2003.-- Supporting information available at: http://pubs.acs.org/doi/suppl/10.1021/ol035611l | Versión del editor: | http://dx.doi.org/10.1021/ol035611l | URI: | http://hdl.handle.net/10261/16764 | DOI: | 10.1021/ol035611l | ISSN: | 1523-7060 |
| Aparece en las colecciones: | (IPNA) Artículos |
Mostrar el registro completo
CORE Recommender
SCOPUSTM
Citations
37
checked on 20-abr-2024
WEB OF SCIENCETM
Citations
30
checked on 23-feb-2024
Page view(s)
377
checked on 21-abr-2024
Google ScholarTM
Check
Altmetric
Altmetric
NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.