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Intramolecular 1,8-hydrogen abstraction between glucopyranose units in a disaccharide model promoted by alkoxy radicals

AuthorsFrancisco, Cosme G. ; Herrera, Antonio J. ; Kennedy, Alan R.; Melián, Daniel; Suárez, Ernesto
Conformation analysis
Hydrogen transfer
Radical reactions
Issue DateMar-2002
PublisherJohn Wiley & Sons
CitationAngewandte Chemie International Edition 41(5): 856-858 (2002)
AbstractThe use of radical reactions in carbohydrate chemistry has recently attracted considerable attention in the synthetic community. Among free radical reactions intramolecular hydrogen abstraction (IHA) has been comparatively less studied in these systems.
Description3 pages, 3 schemes.-- PMID: 12491359 [PubMed].-- Supporting information available at: http://www.wiley-vch.de/contents/jc_2002/2002/z18262_s.pdf
Publisher version (URL)http://dx.doi.org/10.1002/1521-3773(20020301)41:5<856::AID-ANIE856>3.0.CO;2-F
Appears in Collections:(IPNA) Artículos
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