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Title: | Electronic interactions in illuminated carbon dots/MoS2 ensembles and electrocatalytic activity towards hydrogen evolution |
Authors: | Canton-Vitoria, Rubén; Vallan, Lorenzo; Urriolabeitia, Esteban P. ![]() |
Keywords: | Layered transition metal dichalcogenides Carbon dots Electrostatic interactions |
Issue Date: | 15-May-2018 |
Publisher: | Wiley-VCH |
Citation: | Chemistry - A European Journal 24(41): 10468-10474 (2018) |
Abstract: | We report on the preparation, characterization and photophysical and electrocatalytic properties of carbon dots (CDs)/MoS2 ensembles. Based on electrostatic interactions, ammonium functionalized MoS2, prepared upon reaction of 1,2-dithiolane tertbutyl carbamate with MoS2 followed by acidic deprotection, was coupled with CDs bearing multiple carboxylates on their periphery as derived upon microwave-assisted polycondensation of citric acid and ethylenediamine followed by alkaline treatment. Insights into electronic interactions between the two species within CDs/MoS2 emanated from absorption and photoluminescence titration assays. Efficient fluorescence quenching of CDs by MoS2 was observed and attributed to photoinduced electron/energy transfer as the decay mechanism for the transduction of the singlet excited state of CDs. Finally, the electrocatalytic performance of CDs/MoS2 was assessed towards the hydrogen evolution reaction and found superior as compared to that owed to the individual CDs species. |
Publisher version (URL): | https://doi.org/10.1002/chem.201801425 |
URI: | http://hdl.handle.net/10261/166481 |
DOI: | http://dx.doi.org/10.1002/chem.201801425 |
ISSN: | 0947-6539 |
Appears in Collections: | (ICB) Artículos (ISQCH) Artículos |
Files in This Item:
File | Description | Size | Format | |
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Postprint Chem Eur. J.-2018.pdf | 2,72 MB | Adobe PDF | ![]() View/Open | |
Submitted Manuscript.pdf | 768,9 kB | Adobe PDF | ![]() View/Open |
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