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Título: | The structure, chemistry and magnetic properties of FePbBiO4 |
Autor: | de Laune, Benjamin P.; Berry, F.J.; Marco, J.F. CSIC ORCID CVN ; Horswell, S.L.; Greaves, C. | Fecha de publicación: | 2016 | Citación: | Journal of Materials Chemistry C 4: 5320- 5325 (2016) | Resumen: | The compound FePbBiO has been synthesised and has a tetragonal structure (P4/mbc, a = 8.48924(9) Å, c = 6.10597(8) Å) that is closely related to FeSbO. It provides the first example of a compound with this structure that (a) contains only trivalent ions (here Fe) within the chains of edge-linked octahedra and (b) accommodates Bi in the walls of the channels formed between the chains of octahedra. FePbBiO orders antiferromagnetically with a Néel temperature of 24 K; neutron diffraction reveals A-type magnetic order with moments oriented perpendicular to [001]. The magnetic moment of Fe at 4 K is 3.74(6) μ, slightly lower than that commonly observed for this cation in well-ordered magnetic oxides. | URI: | http://hdl.handle.net/10261/166109 | DOI: | 10.1039/c6tc01034b | Identificadores: | doi: 10.1039/c6tc01034b issn: 2050-7526 |
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