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Metal-driven assembly of peptidic foldamers: Formation of molecular tapes

AutorSolà Oller, Jordi ; Bolte, Michael; Alfonso, Ignacio
Palabras clavePeptides
Synthesis of supramolecular metal-organic structures
SEM-EDS
Fecha de publicación18-abr-2016
EditorRoyal Society of Chemistry (Great Britain)
CitaciónCrystEngComm 18 (21): 3793-3798 (2016)
ResumenIn this article, we report the use of a peptidic foldamer in the synthesis of supramolecular metal-organic structures. A peptidic ligand was designed and synthesised to adopt a canonical 310 helix with pyridyl ligands at each end, as confirmed by X-ray diffraction analysis. The combination of the synthesised peptide and silver salts under adequate reaction conditions results in the production of coordination polymers. The materials thus produced have been analysed by means of SEM-EDS, confirming the formation of long, regular, tape-shaped fibres that contain both the organic moiety and the metal atom. ATR FT-IR spectroscopy suggests that the helical structure of the peptide is preserved within the fibre. © 2016 The Royal Society of Chemistry.
Versión del editor10.1039/c6ce00601a
URIhttp://hdl.handle.net/10261/164745
DOI10.1039/c6ce00601a
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