Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/164405
COMPARTIR / EXPORTAR:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Título: | The Curious Case of 2-Propyl-1H-benzimidazole in the Solid State: An Experimental and Theoretical Study |
Autor: | Quesada-Moreno, María Mar; Cruz-Cabeza, A. J.; Avilés-Moreno, Juan Ramón; Cabildo, Pilar; Claramunt, Rosa M.; Alkorta, Ibon CSIC ORCID ; Elguero, José CSIC ORCID; Zúñiga, F. J.; López-González, Juan Jesús | Fecha de publicación: | 2017 | Editor: | American Chemical Society | Citación: | The journal of physical chemistry, A, Molecules, spectroscopy, kinetics, environment & general theory 121: 5665-5674 (2017) | Resumen: | 2-Propyl-1H-benzimidazole (2PrBzIm) is a small molecule, commercially available, which displays a curious behavior in the solid state. 2PrBzIm, although devoid of chirality by fast rotation about a single bond of the propyl group in solution, crystallizes as a conglomerate showing chiroptical properties. An exhaustive analysis of its crystal structure and a wide range of experiments monitored by vibrational circular dichroism spectroscopy eliminated all possibilities of an artifact. What remains is a new example of the unexplained phenomenon of persistent supramolecular chirality. | Versión del editor: | http://dx.doi.org/10.1021/acs.jpca.7b05220 | URI: | http://hdl.handle.net/10261/164405 | DOI: | 10.1021/acs.jpca.7b05220 | Identificadores: | doi: 10.1021/acs.jpca.7b05220 issn: 1089-5639 e-issn: 1520-5215 |
Aparece en las colecciones: | (IQM) Artículos |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
---|---|---|---|---|
accesoRestringido.pdf | 15,38 kB | Adobe PDF | Visualizar/Abrir |
CORE Recommender
SCOPUSTM
Citations
12
checked on 17-abr-2024
WEB OF SCIENCETM
Citations
12
checked on 25-feb-2024
Page view(s)
281
checked on 24-abr-2024
Download(s)
89
checked on 24-abr-2024
Google ScholarTM
Check
Altmetric
Altmetric
NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.