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dc.contributor.authorVan Schie, M.M.C.H.es_ES
dc.contributor.authorDe Almeida, T.P.es_ES
dc.contributor.authorLaudadio, G.es_ES
dc.contributor.authorTieves, Florianes_ES
dc.contributor.authorFernández-Fueyo, Elenaes_ES
dc.contributor.authorNoël, T.es_ES
dc.contributor.authorArends, I.W.C.E.es_ES
dc.contributor.authorHollmann, Frankes_ES
dc.date.accessioned2018-04-30T12:32:55Z-
dc.date.available2018-04-30T12:32:55Z-
dc.date.issued2018-03-26-
dc.identifier.citationBeilstein Journal of Organic Chemistry 14:697-703 (2018)es_ES
dc.identifier.issn1860-5397-
dc.identifier.urihttp://hdl.handle.net/10261/164344-
dc.description7 p.-1 schem.-3 fig.-1 tab.es_ES
dc.description.abstractThe biocatalytic preparation of trans-hex-2-enal from trans-hex-2-enol using a novel aryl alcohol oxidase from Pleurotus eryngii (PeAAOx) is reported. As O2-dependent enzyme PeAAOx-dependent reactions are generally plagued by the poor solubility of O2 in aqueous media and mass transfer limitations resulting in poor reaction rates. These limitations were efficiently overcome by conducting the reaction in a flow-reactor setup reaching unpreceded catalytic activities for the enzyme in terms of turnover frequency (up to 38 s-1) and turnover numbers (more than 300000) pointing towards preparative usefulness of the proposed reaction scheme.es_ES
dc.description.sponsorshipWe thank the Netherlands Organisation for Scientific Research for financial support through a VICI grant (no. 724.014.003).es_ES
dc.language.isoenges_ES
dc.publisherTaylor & Francises_ES
dc.relation.isversionofPublisher's versiones_ES
dc.rightsopenAccesses_ES
dc.subjectAlcohol oxidasees_ES
dc.subjectAlcohol oxidationes_ES
dc.subjectAldehydees_ES
dc.subjectFlow chemistryes_ES
dc.titleBiocatalytic synthesis of the Green Note trans-2-hexenal in a continuous-flow microreactores_ES
dc.typeartículoes_ES
dc.identifier.doihttp://dx.doi.org/10.3762/bjoc.14.58-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttp://dx.doi.org/10.3762/bjoc.14.58es_ES
dc.identifier.e-issn1860-5397-
dc.rights.licensehttps://creativecommons.org/licenses/by/4.0/es_ES
dc.contributor.funderNetherlands Organization for Scientific Researches_ES
dc.relation.csices_ES
oprm.item.hasRevisionno ko 0 false*
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