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Title

Biocatalytic synthesis of the Green Note trans-2-hexenal in a continuous-flow microreactor

AuthorsVan Schie, M.M.C.H.; De Almeida, T.P.; Laudadio, G.; Tieves, Florian; Fernández-Fueyo, Elena ; Noël, T.; Arends, I.W.C.E.; Hollmann, Frank
KeywordsAlcohol oxidase
Alcohol oxidation
Aldehyde
Flow chemistry
Issue Date26-Mar-2018
PublisherTaylor & Francis
CitationBeilstein Journal of Organic Chemistry 14:697-703 (2018)
AbstractThe biocatalytic preparation of trans-hex-2-enal from trans-hex-2-enol using a novel aryl alcohol oxidase from Pleurotus eryngii (PeAAOx) is reported. As O2-dependent enzyme PeAAOx-dependent reactions are generally plagued by the poor solubility of O2 in aqueous media and mass transfer limitations resulting in poor reaction rates. These limitations were efficiently overcome by conducting the reaction in a flow-reactor setup reaching unpreceded catalytic activities for the enzyme in terms of turnover frequency (up to 38 s-1) and turnover numbers (more than 300000) pointing towards preparative usefulness of the proposed reaction scheme.
Description7 p.-1 schem.-3 fig.-1 tab.
Publisher version (URL)http://dx.doi.org/10.3762/bjoc.14.58
URIhttp://hdl.handle.net/10261/164344
DOIhttp://dx.doi.org/10.3762/bjoc.14.58
ISSN1860-5397
E-ISSN1860-5397
Appears in Collections:(CIB) Artículos
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