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Title

Hypervalent organoiodine reagents in the transannular functionalisation of medium-sized lactams: synthesis of 1-azabicyclo compounds

AuthorsDorta, Rosa L. ; Francisco, Cosme G. ; Suárez, Ernesto
Issue Date1989
PublisherRoyal Society of Chemistry (UK)
CitationChemical Communications 1989(16): 1168-1169 (1989)
AbstractThe amidyl radical intermediates, produced by photolysis of medium-sized lactams 7-heptanelactam (1), 8-octanelactam (3), and 9-nonanelactam (6) in the presence of (diacetoxyiodo)benzene (DIB) and iodine, undergo transannular hydrogen abstraction to afford intermolecularly functionalised compounds such as oxoindolizidines (4) and (5) and the 1-azabicyclo[5.3.0]decan-2-one (7) that are obtained in high yield from lactams (3) and (6), respectively.
Description2 pages, 1 table, 1 scheme.
Publisher version (URL)http://dx.doi.org/10.1039/C39890001168
URIhttp://hdl.handle.net/10261/16432
DOI10.1039/C39890001168
ISSN1359-7345
Appears in Collections:(IPNA) Artículos
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