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Intramolecular hydrogen abstraction. The use of organoselenium reagents for the generation of alkoxy radicals

AuthorsDorta, Rosa L. ; Francisco, Cosme G. ; Freire, Raimundo ; Suárez, Ernesto
Issue Date1988
CitationTetrahedron Letters 29(42): 5429-5432 (1988)
AbstractThe alkoxy radical intermediates, produced by photolysis of several hydroxy compounds in the presence of diphenylselenuranes (1) and iodine, undergo intramolecular hydrogen abstraction to afford cyclic ethers in good yield.
Description4 pages, 1 table, 1 scheme.
Publisher version (URL)http://dx.doi.org/10.1016/S0040-4039(00)82887-7
Appears in Collections:(IPNA) Artículos
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