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Título: | The reaction between triphenylphosphine and methyl 2-bromoalkanoates |
Autor: | Pórtulas, Joan; Sánchez, Francisco; Sánchez-Pardo, Josep CSIC | Fecha de publicación: | oct-1976 | Editor: | Elsevier | Citación: | Tetrahedron Letters 17(40): 3617-3618 (1976) | Resumen: | Because of the versatile applications of the Wittig reaction, the Touer (1-nethoxycarbonylalkvl)triphenylphosphonium bromides 1 (R * H, Ne) are uell characterized, useful synthetic intermediates. The higher members of the series, however, have I not been isolated, with the exception of ethyl esters 1 (R * Et or n-Bu, ethyl esters instead of methyl esters)1, 2. On the other hand, the obvious preparation of salts 1, namely the reaction between triphenylphosphine 2 and a methyl 2-bromoalkanoate 3, has not been the subject of a systematic study, although it can be concluded from literature data that vigorous reaction conditions and/or long reaction times are needed for the preparation of the higher members of the series 3. Finally, it is also known that several salts of type 1 (R - H, Ph, Ac) can decompose thermally 4.5, givlng methyl bromide, carbon dioxide, ylid 6 and salt 7 (Scheme) | Descripción: | 2 pages, 1 table | Versión del editor: | https://doi.org/10.1016/S0040-4039(00)92975-7 | URI: | http://hdl.handle.net/10261/163841 | DOI: | 10.1016/S0040-4039(00)92975-7 | ISSN: | 0040-4039 |
Aparece en las colecciones: | (IIP) Artículos |
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