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dc.contributor.authorAbdellaoui, Sofienees_ES
dc.contributor.authorMacazo, Florika C.es_ES
dc.contributor.authorCai, Ronges_ES
dc.contributor.authorLópez de Lacey, Antonioes_ES
dc.contributor.authorPita, Marcoses_ES
dc.contributor.authorMinteer, Shelleyes_ES
dc.date.accessioned2018-04-19T09:16:54Z-
dc.date.available2018-04-19T09:16:54Z-
dc.date.issued2018-02-23-
dc.identifier.citationAngewandte Chemie International Edition 57(9): 2404-2408 (2018)es_ES
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10261/163823-
dc.description.abstractAn enzymatic electrosynthesis system was created by combining an aldehyde deformylating oxygenase (ADO) from cyanobacteria that catalyzes the decarbonylation of fatty aldehydes to alkanes and formic acid with an electrochemical interface. This system is able to produce a range of alkanes (octane to propane) from aldehydes and alcohols. The combination of this bioelectrochemical system with a hydrogenase bioanode yields a H2/heptanal enzymatic fuel cell (EFC) able to simultaneously generate electrical energy with a maximum current density of 25 μA cm−2 at 0.6 V and produce hexane with a faradaic efficiency of 24 %.es_ES
dc.description.sponsorshipWe thank the Army Research Office MURI grant (#W911NF1410263), the Korea Institute of Energy Technology Evaluation and Planning (20142020200980), and the Spanish Economy Ministry (MINECO/FEDER CTQ2015‐71290‐R grant) for funding.es_ES
dc.language.isoenges_ES
dc.publisherJohn Wiley & Sonses_ES
dc.relationMINECO/ICTI2013-2016/CTQ2015‐71290‐Res_ES
dc.rightsclosedAccesses_ES
dc.titleEnzymatic Electrosynthesis of Alkanes by Bioelectrocatalytic Decarbonylation of Fatty Aldehydeses_ES
dc.typeartículoes_ES
dc.identifier.doi10.1002/anie.201712890-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttps://doi.org/10.1002/anie.201712890es_ES
dc.identifier.e-issn1521-3773-
dc.contributor.funderMultidisciplinary University Research Initiative (US)es_ES
dc.contributor.funderKorea Institute of Energy Technologyes_ES
dc.contributor.funderMinisterio de Economía y Competitividad (España)es_ES
dc.contributor.funderEuropean Commissiones_ES
dc.relation.csices_ES
oprm.item.hasRevisionno ko 0 false*
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000780es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
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