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dc.contributor.authorBernardo-Maestro, Beatrizes_ES
dc.contributor.authorGarrido-Martín, Elisaes_ES
dc.contributor.authorLópez-Arbeloa, Fernandoes_ES
dc.contributor.authorPérez-Pariente, Joaquínes_ES
dc.contributor.authorGómez-Hortigüela Sainz, Luises_ES
dc.date.accessioned2018-03-19T08:07:06Z-
dc.date.available2018-03-19T08:07:06Z-
dc.date.issued2018-03-15-
dc.identifier.citationPhysical Chemistry Chemical Physics13: 8564-8578 (2018)es_ES
dc.identifier.issn1463-9076-
dc.identifier.urihttp://hdl.handle.net/10261/162386-
dc.description.abstractIn an attempt to promote the crystallization of chiral inorganic frameworks, we explore the ability of chiral (1R,2S)-ephedrine and its diastereoisomer (1S,2S)-pseudoephedrine to act as organic building blocks for the crystallization of hybrid organo-inorganic aluminophosphate frameworks in the presence of fluoride. These molecules were selected because of their particular molecular asymmetric structure, which enables a rich supramolecular chemistry and a potential chiral recognition phenomenon during crystallization. Up to four new low-dimensional materials have been produced, wherein the organic molecules form an organic bilayer in-between the inorganic networks. We analyze by molecular simulations the trend of these chiral molecules to form these types of framework, which is directly related to their amphiphilic nature that triggers a strong self-assembly through hydrophobic interactions between aromatic rings and hydrophilic interactions with the fluoro-aluminophosphate inorganic units. Such a self-assembly process is strongly dependent on the concentration of the organic molecules.es_ES
dc.description.sponsorshipThis work has been partially financed by the Spanish Ministry of Economy, Industry and Competitiveness (Project MAT2015-65767-P) and the Spanish State Research Agency (Agencia Española de Investigación, AEI) and the European Regional Development Fund (Fondo Europeo de Desarrollo Regional, FEDER) through the Project MAT2016-77496-R (AEI/FEDER, UE). BBM acknowledges the Spanish Ministry of Economy and Competitivity for a predoctoral (BES-2013-064605) contract. Secretaría General Adjunta de Informática-CSIC is acknowledged for running the calculations, and BIOVIA for providing the computational software.es_ES
dc.language.isoenges_ES
dc.publisherRoyal Society of Chemistry (UK)es_ES
dc.relationinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2015-65767-Pes_ES
dc.relationinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2016-77496-Res_ES
dc.relation.isversionofPostprintes_ES
dc.rightsopenAccessen_EN
dc.subjectAluminophosphateses_ES
dc.subjectEphedrinees_ES
dc.subjectPseudoephedrinees_ES
dc.subjectSupramoleculares_ES
dc.subjectSelf-assemblyes_ES
dc.subjectChiralityes_ES
dc.titleSelf-assembly of chiral (1R,2S)-ephedrine and (1S,2S)-pseudoephedrine into low-dimensional aluminophosphate materials driven by their amphiphilic naturees_ES
dc.typeartículoes_ES
dc.identifier.doi10.1039/c7cp08573g-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttp://dx.doi.org/10.1039/c7cp08573ges_ES
dc.identifier.e-issn1463-9084-
dc.embargo.terms2019-05-15es_ES
dc.contributor.funderMinisterio de Economía, Industria y Competitividad (España)es_ES
dc.contributor.funderEuropean Commissiones_ES
dc.contributor.funderEuropean Commissiones_ES
dc.contributor.funderMinisterio de Economía y Competitividad (España)es_ES
dc.contributor.funderConsejo Superior de Investigaciones Científicas (España)es_ES
dc.relation.csices_ES
oprm.item.hasRevisionno ko 0 false*
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000780es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003339es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100010198es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
dc.type.coarhttp://purl.org/coar/resource_type/c_6501es_ES
item.openairetypeartículo-
item.cerifentitytypePublications-
item.languageiso639-1en-
item.grantfulltextopen-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.fulltextWith Fulltext-
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