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http://hdl.handle.net/10261/162386
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Bernardo-Maestro, Beatriz | es_ES |
dc.contributor.author | Garrido-Martín, Elisa | es_ES |
dc.contributor.author | López-Arbeloa, Fernando | es_ES |
dc.contributor.author | Pérez-Pariente, Joaquín | es_ES |
dc.contributor.author | Gómez-Hortigüela Sainz, Luis | es_ES |
dc.date.accessioned | 2018-03-19T08:07:06Z | - |
dc.date.available | 2018-03-19T08:07:06Z | - |
dc.date.issued | 2018-03-15 | - |
dc.identifier.citation | Physical Chemistry Chemical Physics13: 8564-8578 (2018) | es_ES |
dc.identifier.issn | 1463-9076 | - |
dc.identifier.uri | http://hdl.handle.net/10261/162386 | - |
dc.description.abstract | In an attempt to promote the crystallization of chiral inorganic frameworks, we explore the ability of chiral (1R,2S)-ephedrine and its diastereoisomer (1S,2S)-pseudoephedrine to act as organic building blocks for the crystallization of hybrid organo-inorganic aluminophosphate frameworks in the presence of fluoride. These molecules were selected because of their particular molecular asymmetric structure, which enables a rich supramolecular chemistry and a potential chiral recognition phenomenon during crystallization. Up to four new low-dimensional materials have been produced, wherein the organic molecules form an organic bilayer in-between the inorganic networks. We analyze by molecular simulations the trend of these chiral molecules to form these types of framework, which is directly related to their amphiphilic nature that triggers a strong self-assembly through hydrophobic interactions between aromatic rings and hydrophilic interactions with the fluoro-aluminophosphate inorganic units. Such a self-assembly process is strongly dependent on the concentration of the organic molecules. | es_ES |
dc.description.sponsorship | This work has been partially financed by the Spanish Ministry of Economy, Industry and Competitiveness (Project MAT2015-65767-P) and the Spanish State Research Agency (Agencia Española de Investigación, AEI) and the European Regional Development Fund (Fondo Europeo de Desarrollo Regional, FEDER) through the Project MAT2016-77496-R (AEI/FEDER, UE). BBM acknowledges the Spanish Ministry of Economy and Competitivity for a predoctoral (BES-2013-064605) contract. Secretaría General Adjunta de Informática-CSIC is acknowledged for running the calculations, and BIOVIA for providing the computational software. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Royal Society of Chemistry (UK) | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2015-65767-P | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2016-77496-R | es_ES |
dc.relation.isversionof | Postprint | es_ES |
dc.rights | openAccess | en_EN |
dc.subject | Aluminophosphates | es_ES |
dc.subject | Ephedrine | es_ES |
dc.subject | Pseudoephedrine | es_ES |
dc.subject | Supramolecular | es_ES |
dc.subject | Self-assembly | es_ES |
dc.subject | Chirality | es_ES |
dc.title | Self-assembly of chiral (1R,2S)-ephedrine and (1S,2S)-pseudoephedrine into low-dimensional aluminophosphate materials driven by their amphiphilic nature | es_ES |
dc.type | artículo | es_ES |
dc.identifier.doi | 10.1039/c7cp08573g | - |
dc.description.peerreviewed | Peer reviewed | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1039/c7cp08573g | es_ES |
dc.identifier.e-issn | 1463-9084 | - |
dc.embargo.terms | 2019-05-15 | es_ES |
dc.contributor.funder | Ministerio de Economía, Industria y Competitividad (España) | es_ES |
dc.contributor.funder | European Commission | es_ES |
dc.contributor.funder | European Commission | es_ES |
dc.contributor.funder | Ministerio de Economía y Competitividad (España) | es_ES |
dc.contributor.funder | Consejo Superior de Investigaciones Científicas (España) | es_ES |
dc.relation.csic | Sí | es_ES |
oprm.item.hasRevision | no ko 0 false | * |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000780 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003339 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100010198 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003329 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.cerifentitytype | Publications | - |
item.languageiso639-1 | en | - |
item.grantfulltext | open | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | With Fulltext | - |
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