English   español  
Por favor, use este identificador para citar o enlazar a este item: http://hdl.handle.net/10261/162386
COMPARTIR / IMPACTO:
Estadísticas
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:
Título

Self-assembly of chiral (1R,2S)-ephedrine and (1S,2S)-pseudoephedrine into low-dimensional aluminophosphate materials driven by their amphiphilic nature

AutorBernardo-Maestro, Beatriz; Garrido-Martín, Elisa; López-Arbeloa, Fernando; Pérez Pariente, Joaquín ; Gómez-Hortigüela Sainz, Luis
Palabras claveAluminophosphate
Ephedrine
Pseudoephedrine
Supramolecular
Self-assembly
Chirality
Fecha de publicación15-mar-2018
EditorRoyal Society of Chemistry (Great Britain)
CitaciónPhysical Chemistry Chemical Physics13: 8564-8578 (2018)
ResumenIn an attempt to promote the crystallization of chiral inorganic frameworks, we explore the ability of chiral (1R,2S)-ephedrine and its diastereoisomer (1S,2S)-pseudoephedrine to act as organic building blocks for the crystallization of hybrid organo-inorganic aluminophosphate frameworks in the presence of fluoride. These molecules were selected because of their particular molecular asymmetric structure, which enables a rich supramolecular chemistry and a potential chiral recognition phenomenon during crystallization. Up to four new low-dimensional materials have been produced, wherein the organic molecules form an organic bilayer in-between the inorganic networks. We analyze by molecular simulations the trend of these chiral molecules to form these types of framework, which is directly related to their amphiphilic nature that triggers a strong self-assembly through hydrophobic interactions between aromatic rings and hydrophilic interactions with the fluoro-aluminophosphate inorganic units. Such a self-assembly process is strongly dependent on the concentration of the organic molecules.
Versión del editorhttp://dx.doi.org/10.1039/c7cp08573g
URIhttp://hdl.handle.net/10261/162386
DOI10.1039/c7cp08573g
ISSN1463-9076
E-ISSN1463-9084
Aparece en las colecciones: (ICP) Artículos
Ficheros en este ítem:
Fichero Descripción Tamaño Formato  
amphiphilic_nature.pdf Embargado hasta 15 de mayo de 20194,04 MBAdobe PDFVista previa
Visualizar/Abrir     Petición de una copia
Mostrar el registro completo
 

Artículos relacionados:


NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.