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http://hdl.handle.net/10261/162380
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dc.contributor.author | Wanmolee, Wanwitoo | es_ES |
dc.contributor.author | Laosiripojana, N. | es_ES |
dc.contributor.author | Daorattanachai, Pornlada | es_ES |
dc.contributor.author | Moghaddam, L. | es_ES |
dc.contributor.author | Rencoret, Jorge | es_ES |
dc.contributor.author | Río Andrade, José Carlos del | es_ES |
dc.contributor.author | Doherty, W.O.S. | es_ES |
dc.date.accessioned | 2018-03-19T06:52:07Z | - |
dc.date.available | 2018-03-19T06:52:07Z | - |
dc.date.issued | 2018-01-30 | - |
dc.identifier.citation | ACS Sustainable Chemistry and Engineering 6(3): 3010–3018 (2018) | es_ES |
dc.identifier.uri | http://hdl.handle.net/10261/162380 | - |
dc.description | 9 páginas.-- 8 figuras.-- 2 tablas.-- 35 referencias.-- The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acssuschemeng.7b02721 | es_ES |
dc.description.abstract | Catalytic depolymerization of organosolv lignin to phenolic monomers with zeolites was investigated under various operating conditions. H-USY (Si/Al molar ratio = 5) outperformed H-USY with Si/Al ratios of 50 and 250, H-BEA, H-ZSM5, and fumed SiO2 to produce the highest phenolic monomer yield from a commercial organosolv lignin in methanol at 300 °C for 1 h. It was then further investigated in the presence of acetone, ethyl acetate, methanol, and methyl isobutyl ketone (MIBK) on the depolymerization of organosolv bagasse lignin (BGL). The total highest phenolic monomer yield of 10.6 wt % was achieved with MIBK at 350 °C for 1 h with a catalyst loading of 10 wt %. A final total phenolic monomer yield of 19.4 wt % was obtained with an initial H2 pressure of 2 MPa under similar processing conditions. The main phenolic monomers obtained are guaiacol (7.9 wt %), 4-ethylphenol (6.0 wt %), and phenol (3.4 wt %). The solvent properties were used to account for the differences in phenolic monomer yields obtained with different organic solvents. | es_ES |
dc.description.sponsorship | The authors express their sincere appreciation to the Joint raduate School of Energy and Environment (JGSEE), Petchra Pra Jom Klao Doctoral Scholarship, King Mongkut’s University of Technology Thonburi (KMUTT), Thailand Research Fund (RTA5980006), and the Queensland University of Technology (QUT), Australia, for financing this project. The authors thank Dr. Jorge Rencoret and Dr. Ana Gutierrez, who were partly funded by the Spanish projects AGL2014-53730-R and CTQ2014-60764-JIN (cofinanced by FEDER funds), for PyGC/MS analysis of the lignins. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | American Chemical Society | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/AGL2014-53730-R | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2014-60764-JIN | es_ES |
dc.rights | closedAccess | es_ES |
dc.subject | Catalyst | es_ES |
dc.subject | Depolymerization | es_ES |
dc.subject | Lignin | es_ES |
dc.subject | MIBK solvent | es_ES |
dc.subject | Phenolic monomers | es_ES |
dc.subject | Zeolites | es_ES |
dc.title | Catalytic Conversion of Organosolv Lignins to Phenolic Monomers in Different Organic Solvents and Effect of Operating Conditions on Yield with Methyl Isobutyl Ketone | es_ES |
dc.type | artículo | es_ES |
dc.identifier.doi | 10.1021/acssuschemeng.7b02721 | - |
dc.description.peerreviewed | Peer reviewed | es_ES |
dc.relation.publisherversion | http://dx.doi.org/10.1021/acssuschemeng.7b02721 | es_ES |
dc.identifier.e-issn | 2168-0485 | - |
dc.contributor.funder | Ministerio de Economía y Competitividad (España) | es_ES |
dc.contributor.funder | European Commission | es_ES |
dc.relation.csic | Sí | es_ES |
oprm.item.hasRevision | no ko 0 false | * |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000780 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003329 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.languageiso639-1 | en | - |
item.fulltext | No Fulltext | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | none | - |
item.openairetype | artículo | - |
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