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Synthesis of nano-SSZ-13 and its application in the reaction of methanol to olefins

AutorLi, Zhibin; Navarro, María Teresa; Martínez Triguero, Joaquín; Yu, Jihong; Corma, Avelino
Fecha de publicación2016
EditorRoyal Society of Chemistry (Great Britain)
CitaciónCatalysis Science and Technology 6(15): 5856-5863 (2016)
ResumenNanosized SSZ-13 has been obtained from a one-pot synthesis procedure with the addition of CTAB to the synthesis precursor solution. Nano-SSZ-13 zeolite showed high intracrystalline mesoporosity and compared to standard SSZ-13 presented a much longer lifetime and higher conversion capacity for the reaction of methanol to olefins. The improved properties were attributed to a more efficient utilization of micropores by easier diffusion of reactants and products and slower deactivation by coke. A higher C2/C3 ratio was found for nano-SSZ-13, pointing to a lower deactivation of the aromatics cycle of the hydrocarbon pool.
Versión del editorhttps://doi.org/10.1039/C6CY00433D
URIhttp://hdl.handle.net/10261/162216
Identificadoresdoi: 10.1039/C6CY00433D
e-issn: 2044-4761
issn: 2044-4753
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