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Title

Cage-based small-pore catalysts for NH3-SCR prepared by combining bulky organic structure directing agents with modified zeolites as reagents

AuthorsMartín, Nuria; Paris Carrizo, Cecilia Gertrudis; Vennestrøm, Peter N. R.; Thøgersen, Joakim; Moliner Marín, Manuel; Corma, Avelino
KeywordsSmall-pore zeolites
Organic structure directing agents (OSDAs)
Erionite
AFX
NOx abatement
Issue Date2017
PublisherElsevier
CitationApplied Catalysis B: Environmental 217: 125-136 (2017)
AbstractIt has been possible to efficiently synthesize high-silica ERI and AFX zeolites with nano-sized primary crystallites (30–200 nm). This was achieved by using a dicationic and rigid organic structure directing agent (OSDA) that fits within the large cavities of these zeolites, and the use of FAU zeolites as initial Si- and Al-sources. Cu- and Fe-based ERI and AFX materials were prepared following both post-synthetic cation exchange and direct synthesis methodologies, showing good activity for the selective catalytic reduction (SCR) of nitrogen oxide using ammonia. Accelerated hydrothermal ageing of the zeolites at high temperature (i.e. 750 °C) shows the necessity of removing the alkali cations remaining in the zeolites to obtain stable materials. Furthermore, the catalytic performance of the prepared Cu- and Fe-containing AFX catalysts, both before and after ageing treatment, approaches the catalytic activity of Cu- and Fe-CHA.
Publisher version (URL)https://doi.org/10.1016/j.apcatb.2017.05.082
URIhttp://hdl.handle.net/10261/162141
Identifiersdoi: 10.1016/j.apcatb.2017.05.082
issn: 0926-3373
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