Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/161747
COMPARTIR / EXPORTAR:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Título: | De Novo Synthesis of α-Hydroxy Ketones by Gallic Acid-Promoted Aerobic Coupling of Terminal Alkynes with Diazonium Salts |
Autor: | Alcaide, Benito CSIC ORCID; Almendros, Pedro CSIC ORCID ; Fernández, Israel; Herrera, Fernando; Luna, Amparo | Palabras clave: | Alkynes α-hydroxy ketones Selectivity Synthetic methods Metal-free reactions |
Fecha de publicación: | 2017 | Editor: | John Wiley & Sons | Citación: | Chemistry - A European Journal 23: 17227-17230 (2017) | Resumen: | An unprecedented metal-free direct preparation of unprotected α-hydroxy ketones from terminal alkynes under mild conditions with diazonium salts as the arene source and without the requirement of irradiation is described. The process is general and fully compatible with a wide variety of substitution in both reactants. Experimental and computational evidence strongly suggest the involvement of radical species in the transformation. | Versión del editor: | http://dx.doi.org/10.1002/chem.201705106 | URI: | http://hdl.handle.net/10261/161747 | DOI: | 10.1002/chem.201705106 | Identificadores: | doi: 10.1002/chem.201705106 issn: 0947-6539 e-issn: 1521-3765 |
Aparece en las colecciones: | (IQOG) Artículos |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
---|---|---|---|---|
695039.pdf | 290,48 kB | Unknown | Visualizar/Abrir |
CORE Recommender
SCOPUSTM
Citations
5
checked on 13-mar-2024
WEB OF SCIENCETM
Citations
5
checked on 23-feb-2024
Page view(s)
314
checked on 18-mar-2024
Download(s)
336
checked on 18-mar-2024
Google ScholarTM
Check
Altmetric
Altmetric
NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.