Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/161747
Share/Export:
logo share SHARE logo core CORE BASE
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE
Title

De Novo Synthesis of α-Hydroxy Ketones by Gallic Acid-Promoted Aerobic Coupling of Terminal Alkynes with Diazonium Salts

AuthorsAlcaide, Benito CSIC ORCID; Almendros, Pedro CSIC ORCID ; Fernández, Israel; Herrera, Fernando; Luna, Amparo
KeywordsAlkynes
α-hydroxy ketones
Selectivity
Synthetic methods
Metal-free reactions
Issue Date2017
PublisherJohn Wiley & Sons
CitationChemistry - A European Journal 23: 17227-17230 (2017)
AbstractAn unprecedented metal-free direct preparation of unprotected α-hydroxy ketones from terminal alkynes under mild conditions with diazonium salts as the arene source and without the requirement of irradiation is described. The process is general and fully compatible with a wide variety of substitution in both reactants. Experimental and computational evidence strongly suggest the involvement of radical species in the transformation.
Publisher version (URL)http://dx.doi.org/10.1002/chem.201705106
URIhttp://hdl.handle.net/10261/161747
DOI10.1002/chem.201705106
Identifiersdoi: 10.1002/chem.201705106
issn: 0947-6539
e-issn: 1521-3765
Appears in Collections:(IQOG) Artículos

Files in This Item:
File Description SizeFormat
695039.pdf290,48 kBUnknownView/Open
Show full item record
Review this work

SCOPUSTM   
Citations

4
checked on May 18, 2022

WEB OF SCIENCETM
Citations

4
checked on May 15, 2022

Page view(s)

286
checked on May 19, 2022

Download(s)

231
checked on May 19, 2022

Google ScholarTM

Check

Altmetric

Dimensions


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.