Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/160400
COMPARTIR / EXPORTAR:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Título: | Highly efficient mixed Li+ transport in ion gel polycationic electrolytes |
Autor: | Pablos, Jesús L. CSIC ORCID; García García, Nuria CSIC ORCID; Garrido, Leoncio CSIC ORCID; Guzmán, J.; Catalina, Fernando CSIC ORCID ; Corrales, Teresa CSIC ORCID; Tiemblo, Pilar CSIC ORCID | Palabras clave: | Polymerizable ionic liquids Li-ion transport Polycationic electrolytes Ion gel electrolytes Anion-exchange transport |
Fecha de publicación: | 2018 | Editor: | Elsevier | Citación: | Journal of Membrane Science 545: 133-139 (2018) | Resumen: | Outstanding Li conductivity and diffusivity have been achieved in free-standing ion gel electrolytes synthesized by in-situ photopolymerization of 1-(2-methacryloyloxy)ethyl-3-butylimidazolium bis(trifluoromethane sulfonyl)imide (IMMA) and/or poly(ethylene glycol) methacrylate (EGMA), in the presence of the room temperature ionic liquids 1-ethyl-3-methylimidazolium bis(fluorosulfonyl)imide (EMIFSI), 1-butyl-1-methylpyrrolidinium bis(fluorosulfonyl)imide (BMPFSI) and bis(trifluoromethane)sulfonimide lithium salt (LiTFSI). The membranes are easy to handle and thermally stable up to 200 ºC. Those containing IMMA in the polymer chain present liquid-like ionic conductivities (up to 10 mS cm at 25 ºC), and liquid-like Li diffusivities and conductivities (D≈4 × 10 m s, σ≈1.4 mS cm at 25 ºC) unreported so far in a solid electrolyte. D is not only very high but significantly higher than its counteranions’ diffusivity, D or D, a very rare behavior in electrolytes where transport is, in principle, ruled by viscosity. It is proposed that in these polycationic electrolytes the motion of Li occurs via two different transport mechanisms, the well-known viscosity-governed transport and an additional anion-exchange mechanism that enables very fast Li diffusion. This combination has high practical relevance for Li batteries as it implies a high contribution of σ to the overall electrolyte's conductivity, and it constitutes a breakthrough in the design of polymer-based solid electrolytes for Li. | URI: | http://hdl.handle.net/10261/160400 | DOI: | 10.1016/j.memsci.2017.08.073 | Identificadores: | doi: 10.1016/j.memsci.2017.08.073 issn: 1873-3123 |
Aparece en las colecciones: | (ICTP) Artículos |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
---|---|---|---|---|
J. Memb.Sci_2018.pdf | Artículo principal | 1,06 MB | Adobe PDF | Visualizar/Abrir |
CORE Recommender
SCOPUSTM
Citations
28
checked on 09-abr-2024
WEB OF SCIENCETM
Citations
26
checked on 27-feb-2024
Page view(s)
318
checked on 19-abr-2024
Download(s)
7
checked on 19-abr-2024
Google ScholarTM
Check
Altmetric
Altmetric
NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.