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Title

Isotope engineering of van derWaals interactions in hexagonal boron nitride

AuthorsVuong, T. Q P; Cuscó, Ramón ; Artús, Lluís ; Gil, Bernard
KeywordsBoron nitride
Honeycomb structures
Nitrides
Quantum electronics
Quantum theory
Van der Waals forces
Issue DateDec-2017
PublisherNature Publishing Group
CitationNature Materials, 17(2): 152-158 (2018)
AbstractHexagonal boron nitride is a model lamellar compound where weak, non-local van der Waals interactions ensure the vertical stacking of two-dimensional honeycomb lattices made of strongly bound boron and nitrogen atoms. We study the isotope engineering of lamellar compounds by synthesizing hexagonal boron nitride crystals with nearly pure boron isotopes (10B and 11B) compared to those with the natural distribution of boron (20 at% 10B and 80 at% 11B). On the one hand, as with standard semiconductors, both the phonon energy and electronic bandgap varied with the boron isotope mass, the latter due to the quantum effect of zero-point renormalization. On the other hand, temperature-dependent experiments focusing on the shear and breathing motions of adjacent layers revealed the specificity of isotope engineering in a layered material, with a modification of the van der Waals interactions upon isotope purification. The electron density distribution is more diffuse between adjacent layers in 10BN than in 11BN crystals. Our results open perspectives in understanding and controlling van der Waals bonding in layered materials. © 2017 Macmillan Publishers Limited, part of Springer Nature. All rights reserved.
DescriptionT.Q.P. Vuong et. al.
Publisher version (URL)http://dx.doi.org/0.1038/NMAT5048
URIhttp://hdl.handle.net/10261/160160
DOI10.1038/NMAT5048
ISSN1476-1122
E-ISSN1476-4660
Appears in Collections:(Geo3Bcn) Artículos
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