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Título: | Synthesis, characterization, and thermoelectric properties of superconducting (BEDT-TTF)2I3 nanoparticles |
Autor: | Chtioui-Gay, Imane; Faulmann, Christophe; Caro, Dominique de; Valade, Lydie; Fraxedas, J. CSIC ORCID ; Ballesteros, Belén CSIC ORCID; Steven, Eden | Fecha de publicación: | 2016 | Editor: | Royal Society of Chemistry (UK) | Citación: | Journal of Materials Chemistry C 4(31): 7449-7454 (2016) | Resumen: | The synthesis of (BEDT-TTF)I in the presence of two neutral amphiphilic molecules [N-octylfurfurylimine and 1-octanamine, N-(2-thienylmethylene)] leads to single and aggregated nanoparticles of 2 to 6 nm size. The samples contain highly crystalline nanoparticles of the β-(BEDT-TTF)I phase, confirmed by XRD. Temperature dependent resistance and magnetic susceptibility studies evidence the superconducting transition characteristics of the β-(BEDT-TTF)I phase. The I-V curve of a single nanoparticle aggregate, measured using AFM, exhibits an expected semiconductor-like behaviour. Thermoelectric studies led to a ZT of 1.47 × 10 at 300 K. | URI: | http://hdl.handle.net/10261/159946 | DOI: | 10.1039/C6TC01378C | Identificadores: | doi: 10.1039/C6TC01378C issn: 2050-7526 |
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