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Switchable surface hydrophobicity–hydrophilicity of a metal–organic framework

AuthorsRodríguez-Hermida, Sabina ; Tsang, Min Ying ; Vignatti, Claudia ; Stylianou, Kyriakos C. ; Guillerm, Vincent ; Pérez-Carvajal, Javier ; Teixidor, Francesc ; Viñas, Clara ; Choquesillo-Lazarte, Duane ; Verdugo, Cristóbal; Peral, Inmaculada; Juanhuix, Jordi; Verdaguer, Albert ; Imaz, Inhar ; Maspoch, Daniel ; Giner Planas, José
Metal–organic frameworks
Surface chemistry
Issue Date2016
CitationAngewandte Chemie International Edition 55(52): 16049-16053 (2016)
AbstractMaterials with surfaces that can be switched from high/superhydrophobicity to superhydrophilicity are useful for myriad applications. Herein, we report a metal–organic framework (MOF) assembled from Zn ions, 1,4-benzenedicarboxylate, and a hydrophobic carborane-based linker. The MOF crystal-surface can be switched between hydrophobic and superhydrophilic through a chemical treatment to remove some of the building blocks.
Identifiersdoi: 10.1002/anie.201609295
e-issn: 1521-3773
issn: 1433-7851
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