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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Campos, Jesús | - |
dc.contributor.author | Nova, Ainara | - |
dc.contributor.author | Kolychev, E.L. | - |
dc.contributor.author | Aldridge, Simon | - |
dc.date.accessioned | 2018-01-29T09:41:11Z | - |
dc.date.available | 2018-01-29T09:41:11Z | - |
dc.date.issued | 2017 | - |
dc.identifier | doi: 10.1002/chem.201702703 | - |
dc.identifier | issn: 1521-3765 | - |
dc.identifier.citation | Chemistry - A European Journal 23: 12655- 12667 (2017) | - |
dc.identifier.uri | http://hdl.handle.net/10261/159777 | - |
dc.description.abstract | Experimental and computational efforts are reported which illuminate the mechanism of a novel boron version of the widespread Negishi coupling reaction that offers a new protocol for the formation of aryl/acyl C−B bonds using a bulky boryl fragment. The role of nucleophilic borylzinc reagents in the reduction of the Pd pre-catalysts to Pd active species has been demonstrated. The non-innocent behavior of the PPh ligands of the [Pd(PPh)Cl] pre-catalyst under activation conditions has been probed both experimentally and computationally, revealing the formation of a trimetallic Pd species bearing bridging phosphide (PPh ) ligands. Our studies also reveal the monoligated formulation of the Pd active species, which led us to synthesize related (η-indenyl)Pd-monophosphine catalysts which show improved catalytic performances under mild conditions. A complete mechanistic proposal to aid future catalyst developments is provided. | - |
dc.publisher | John Wiley & Sons | - |
dc.relation.isversionof | Postprint | - |
dc.rights | openAccess | en_EN |
dc.title | A Combined Experimental/Computational Study of the Mechanism of a Palladium-Catalyzed Bora-Negishi Reaction | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1002/chem.201702703 | - |
dc.embargo.terms | 2018-09-16 | - |
dc.date.updated | 2018-01-29T09:41:11Z | - |
dc.description.version | Peer Reviewed | - |
dc.language.rfc3066 | eng | - |
dc.relation.csic | Sí | - |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.fulltext | With Fulltext | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | open | - |
item.openairetype | artículo | - |
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A Combined Experimental Paper.pdf | 1,27 MB | Adobe PDF | Visualizar/Abrir |
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