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Título

Autothermal chemical looping reforming process of different fossil liquid fuels

AutorGarcía-Díez, Enrique CSIC; García Labiano, Francisco CSIC ORCID ; Diego Poza, Luis F. de CSIC ORCID ; Abad Secades, Alberto CSIC ORCID ; Gayán Sanz, Pilar CSIC ORCID
Palabras claveHydrogen production
CO2 capture
Chemical-looping reforming
Oxygen-carrier
Liquid fuels
Fecha de publicación11-may-2017
EditorElsevier
CitaciónInternational Journal of Hydrogen Energy 42(19): 13633-13640 (2017)
ResumenThe autothermal Chemical-Looping Reforming (a-CLR) is a process where syngas is produced with two main advantages; there are captured CO2 emissions and the heat required for the syngas production is generated by the process itself. A Ni-based material is used as oxygen carrier circulating between two fluidized bed reactors: the fuel and air reactors. In this work, the auto-thermal conditions in a global H2 production process, integrated by the a-CLR process and a Water Gas Shift reactor, using different liquid fossil fuels were theoretically determined. The hydrogen production per mol of carbon in the fuel was similar for all fossil fuels, taking a value of 2.2 at the optimal operating temperature (700 °C). In addition, the possibility of working at low temperature for a maximum H2 production was experimentally demonstrated in a continuous 1 kWth a-CLR unit.
Descripción21st World Hydrogen Energy Conference (WHEC), Zaragoza, SPAIN, JUN 13-16, 2016
Versión del editorhttps://doi.org/10.1016/j.ijhydene.2016.12.109
URIhttp://hdl.handle.net/10261/159487
DOI10.1016/j.ijhydene.2016.12.109
ISSN0360-3199
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