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Ferrocene-functionalized graphene electrode for biosensing applications

AuthorsRabti, Amal; Mayorga-Martínez, Carmen C. ; Baptista-Pires, Luis ; Raouafi, Noureddine; Merkoçi, Arben
KeywordsReduced graphene oxide electrode
Non-enzymatic sensor
Issue Date2016
CitationAnalytica Chimica Acta 926: 28-35 (2016)
AbstractA novel ferrocene-functionalized reduced graphene oxide (rGO)-based electrode is proposed. It was fabricated by the drop casting of ferrocene-functionalized graphene onto polyester substrate as the working electrode integrated within screen-printed reference and counter electrodes. The ferrocene-functionalized rGO has been fully characterized using FTIR, XPS, contact angle measurements, SEM and TEM microscopy, and cyclic voltammetry. The XPS and EDX analysis showed the presence of Fe element related to the introduced ferrocene groups, which is confirmed by a clear CV signal at ca. 0.25 V vs. Ag/AgCl (0.1 KCl). Mediated redox catalysis of HO and bio-functionalization with glucose oxidase for glucose detection were achieved by the bioelectrode providing a proof for potential biosensing applications.
Identifiersdoi: 10.1016/j.aca.2016.04.010
e-issn: 1873-4324
issn: 0003-2670
Appears in Collections:(CIN2) Artículos
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