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http://hdl.handle.net/10261/159415
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Abián, María | es_ES |
dc.contributor.author | Abad Secades, Alberto | es_ES |
dc.contributor.author | Izquierdo Pantoja, María Teresa | es_ES |
dc.contributor.author | Gayán Sanz, Pilar | es_ES |
dc.contributor.author | Diego Poza, Luis F. de | es_ES |
dc.contributor.author | García Labiano, Francisco | es_ES |
dc.contributor.author | Adánez Elorza, Juan | es_ES |
dc.date.accessioned | 2018-01-22T12:41:40Z | - |
dc.date.available | 2018-01-22T12:41:40Z | - |
dc.date.issued | 2017-05-01 | - |
dc.identifier.citation | Fuel 195: 38-48 (2017) | es_ES |
dc.identifier.issn | 0016-236 | - |
dc.identifier.uri | http://hdl.handle.net/10261/159415 | - |
dc.description | © 2017. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ | - |
dc.description.abstract | Mixed oxides of Mn-Fe have been identified as suitable materials for Chemical Looping Combustion (CLC) with solid fuels both via in-situ Gasification Chemical Looping Combustion (iG-CLC) and Chemical Looping with Oxygen Uncoupling (CLOU) processes. These materials show the property of react with gaseous fuels as well as release oxygen under given conditions, while cheap metals are used. In addition, these materials can show magnetic properties that can be used for an easy separation from ash in CLC with solid fuels. Thus, losses of oxygen carrier material in the ash drain stream would be reduced. Different cations have been proposed for improving the magnetic properties of manganese ferrites, including Ti4+. In this context, the present work accomplishes a screening of (MnxFe1−x)2O3 doped with 7 wt.% TiO2, with x ranging from 0 to 1. The influence of Mn:Fe ratio on their physical and chemical properties was evaluated. In general, particles with high crushing strength values (>4 N) were obtained, and magnetic characteristics were highlighted when x ⩽ 0.66. The oxygen uncoupling capability depended on the Mn:Fe ratio and the oxidation conditions, i.e. temperature and oxygen partial pressure. Broader oxidation conditions to take advantage of the oxygen uncoupling capability were found for materials with low Mn content. On contrary, the reactivity with fuel gases (CH4, H2 and CO) increased with the Mn content. Thus, oxygen carriers with Mn/(Mn + Fe) molar ratio in the 0.5–0.9 interval showed interesting properties at suitable temperatures for the iG-CLC and CLOU processes (i.e. 850–980 °C). The material with Mn/(Mn + Fe) = 0.55 was preferred considering a trade-off between reactivity and magnetic properties. | es_ES |
dc.description.sponsorship | This work was partially supported by the Spanish Ministry for Economy and Competitiveness via the ENE2013-45454-R and ENE2014-56857-R projects, by the European Regional Development Fund (ERDF), and by the CSIC via the 2014-80E101 project. M. Abián acknowledges the MINECO and Instituto de Carboquímica (ICB-CSIC) for the post-doctoral grant awarded (FPDI-2013-16172). | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Elsevier | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/ENE2013-45454-R | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/ENE2014-56857-R | es_ES |
dc.relation.isversionof | Postprint | es_ES |
dc.rights | openAccess | en_EN |
dc.subject | CO2 capture | es_ES |
dc.subject | Chemical looping combustion | es_ES |
dc.subject | Oxygen carrier | es_ES |
dc.subject | Manganese oxide | es_ES |
dc.subject | Iron oxide | es_ES |
dc.title | Titanium substituted manganese-ferrite as an oxygen carrier with permanent magnetic properties for chemical looping combustion of solid fuels | es_ES |
dc.type | artículo | es_ES |
dc.identifier.doi | 10.1016/j.fuel.2017.01.030 | - |
dc.description.peerreviewed | Peer reviewed | es_ES |
dc.relation.publisherversion | https://doi.org/10.1016/j.fuel.2017.01.030 | es_ES |
dc.embargo.terms | 2019-05-02 | - |
dc.rights.license | http://creativecommons.org/licenses/by-nc-nd/4.0/ | - |
dc.contributor.funder | Ministerio de Economía y Competitividad (España) | es_ES |
dc.contributor.funder | European Commission | es_ES |
dc.contributor.funder | Consejo Superior de Investigaciones Científicas (España) | es_ES |
dc.relation.csic | Sí | es_ES |
oprm.item.hasRevision | no ko 0 false | * |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003329 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003339 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000780 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.fulltext | With Fulltext | - |
item.languageiso639-1 | en | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.openairetype | artículo | - |
item.cerifentitytype | Publications | - |
item.grantfulltext | open | - |
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4_postprint Fuel 195 (2017) 38_48.pdf | Artículo principal | 810,73 kB | Adobe PDF | Visualizar/Abrir |
1-s2.0-S0016236117300327-mmc1.docx | Información suplementaria | 21,53 kB | Microsoft Word XML | Visualizar/Abrir |
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