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Title

Gold Sulfinyl Mesoionic Carbenes: Synthesis, Structure, and Catalytic Activity

AuthorsFrutos, Mercedes de ; Avello, M. G.; Viso, Alma ; Fernández de la Pradilla, Roberto ; Torre, María C. de la ; Sierra, Miguel A.; Gornitzka, H.; Hemmert, Catherine
Issue Date2016
PublisherAmerican Chemical Society
CitationOrganic Letters 18: 3570-3573 (2016)
AbstractGold mesoionic carbenes having a chiral sulfoxide group attached to the C4 position of the five membered ring have been prepared and tested as catalysts in the cycloisomerization of enynes. These new catalysts are very efficient, with the sulfoxide moiety playing a key role in their activity and the N1-substituent in control of the regioselectivity of these processes.
Publisher version (URL)http://dx.doi.org/10.1021/acs.orglett.6b01555
URIhttp://hdl.handle.net/10261/157457
DOI10.1021/acs.orglett.6b01555
Identifiersdoi: 10.1021/acs.orglett.6b01555
issn: 1523-7060
e-issn: 1523-7052
Appears in Collections:(IQOG) Artículos
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