English   español  
Por favor, use este identificador para citar o enlazar a este item: http://hdl.handle.net/10261/156419
COMPARTIR / IMPACTO:
Estadísticas
logo share SHARE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:
Título

Rhodium catalysts for C-S bond formation

AutorGiuseppe, Andrea di ; Castarlenas, Ricardo ; Oro, Luis A.
Palabras claveCarbothiolation
Thiolation
Thioethers
Hydrothiolation
Halides
Cross coupling
Alkynes
Allenes
C–H activation
Fecha de publicación2016
EditorSpringer Nature
CitaciónTopics in Organometallic Chemistry: 1-37 (2016)
ResumenSulfur-containing molecules are commonly found in chemical biology, organic synthesis, and materials chemistry. The preparation of these compounds through traditional methods usually required harsh reaction conditions. The use of transition-metal-based catalysts has allowed the development of more efficient and sustainable synthetic processes. Rhodium-catalyzed C–S bond formation through the reaction between sulfur sources such as S8, thiols, or disulfides with organic substrates such as alkynes, allenes, and aryl/alkyl halides is one of the most important methods in the synthesis of thioethers. Here, we summarize recent efforts in the reactions of cross coupling, C–H activation, metathesis, thiolation, carbothiolation, and hydrothiolation for the C–S bond formation catalyzed by rhodium complexes, particularly highlighting the synthetic and mechanistic aspects.
URIhttp://hdl.handle.net/10261/156419
DOI10.1007/3418_2016_171
Identificadoresdoi: 10.1007/3418_2016_171
isbn: 978-3-642-32832-9
Aparece en las colecciones: (ISQCH) Libros y partes de libros
Ficheros en este ítem:
Fichero Descripción Tamaño Formato  
accesoRestringido.pdf15,38 kBAdobe PDFVista previa
Visualizar/Abrir
Mostrar el registro completo
 

Artículos relacionados:


NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.