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dc.contributor.authorMartín, Jaimees_ES
dc.contributor.authorGarcía-Yebra, Cristinaes_ES
dc.contributor.authorOñate, Enriquees_ES
dc.contributor.authorEsteruelas, Miguel A.es_ES
dc.identifier.citationX International School On Organometallic Chemistry Marcial Moreno Mañas (2017)es_ES
dc.descriptionResumen del póster presentado a la X International School on Organometallic Chemistry “Marcial Moreno Mañas”, celebrada en Ciudad Real (España) del 5 al 7 de julio de 2017.es_ES
dc.description.abstractDiphosphine pincer ligands develop marked abilities to stabilize metal complexes capable of activating inert bonds. Those based on POP-skeletons have particular interest due to the hemilabile properties of the central oxygen atom. We have recently reported the formation of molecular hydrogen kinetically-controlled by osmium polyhydride complexes stabilized by a POP pincer ligand. During the process, the ligand changes its coordination fashion mode from κ3-fac to κ3-mer to κ2-P,P’ bidentate to form polyhydrides with nonclassical interactions and classical polyhydrides. Related POP osmium systems stabilize elongated σ-borane and σ-borane species towards B-H bond activation. The new osmium-borane complexes have been isolated and their identity confirmed by both spectroscopic characterization and theoretical studies. Here we present our preliminary results in the context of new POP-Osmium polyhydrides with a hydroxide ligand.es_ES
dc.titleRecent developments in the chemistry of osmium complexes with POP-ligandses_ES
dc.typepóster de congresoes_ES
dc.description.peerreviewedPeer reviewedes_ES
oprm.item.hasRevisionno ko 0 false*
Appears in Collections:(ISQCH) Comunicaciones congresos
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