English   español  
Por favor, use este identificador para citar o enlazar a este item: http://hdl.handle.net/10261/156117
COMPARTIR / IMPACTO:
Estadísticas
logo share SHARE   Add this article to your Mendeley library MendeleyBASE
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:
Título

Osmium polyhydrides containing boron ligands

AutorBabón, Juan C.; Esteruelas, Miguel A. ; Fernández, Israel; López, Ana M. ; Oñate, Enrique
Fecha de publicación2017
CitaciónX International School On Organometallic Chemistry Marcial Moreno Mañas (2017)
ResumenThe reactions of B-H bond activation by transition metal complexes is a field of great interest due to its connection with numerous catalytic processes such as hydroboration of unsaturated organic molecules, dehydrogenative borylation of hydrocarbons, and dehydrocoupling of amine-borane derivatives. Among transition metal complexes, polyhydrides of platinum group metals have shown to promote the activation of B-H bonds. Our group has recently shown that hydride osmium complexes not only exhibit a rich reactivity with boranes giving rise to a variety of species such as boryl-dihydrideborate, σ-borinium, σ-borane, and bis-σ-borane, but also catalyses the ammonia-borane and amine-borane adducts dehydrogenation. Herein, we present new polyhydrides of osmium containing boron ligands, which have been characterized in solid state and solution and their bonding situation analysed via DFT calculations.
DescripciónResumen del trabajo presentado a la X International School on Organometallic Chemistry “Marcial Moreno Mañas”, celebrada en Ciudad Real (España) del 5 al 7 de julio de 2017.
URIhttp://hdl.handle.net/10261/156117
Aparece en las colecciones: (ISQCH) Comunicaciones congresos
Ficheros en este ítem:
Fichero Descripción Tamaño Formato  
accesoRestringido.pdf15,38 kBAdobe PDFVista previa
Visualizar/Abrir
Mostrar el registro completo
 


NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.