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Catalytic activity of iridium NHC complexes covalently bonded to carbon nanotubes and graphene oxide

AutorBlanco, Matías ; Álvarez Rodríguez, Patricia ; González Arias, Zoraida ; Blanco Rodríguez, Clara ; Jiménez, M. Victoria ; Fernández-Tornos, Javier ; Pérez-Torrente, Jesús J. ; Oro, Luis A. ; Menéndez López, Rosa María
Fecha de publicación2015
CitaciónCARBON 2015
ResumenCarbon nanotubes and graphene have been extensively applied as proactive supports to generate heterogeneous catalysts. Both exhibit a carbon structure composed by carbon atoms with sp2 hybridization and both are used in similar applications, as in catalysis. However, the role of each particular substrate, determined by its structural peculiarities, can be differentvshould be studied for each particular catalytic reaction and in their structure.The aim of this work is to study the differences between oxidized carbon nanotubes (CNT) and graphene oxides (GO) as proactive supports of iridium Nheterocyclic carbene (NHC) catalyst. The effect of their inherent structure in the catalytic activity in hydrogen transfer reactions was studied in detail.
DescripciónTrabajo presentado a la Annual World Conference on Carbon, celebrada en Dresden (Alemania) del 12 al 17 de julio de 2015.
URIhttp://hdl.handle.net/10261/155963
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