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Title

Efficient preparation of carbamates by Rh-catalysed oxidative carbonylation: unveiling the role of the oxidant

AuthorsIturmendi, Amaia ; Iglesias, Manuel ; Munárriz, Julen; Polo, Víctor; Pérez-Torrente, Jesús J. ; Oro, Luis A.
Issue Date2017
PublisherRoyal Society of Chemistry (UK)
CitationChemical Communications 53(2): 404-407 (2017)
AbstractThe synthesis of a wide variety of carbamates from amines, alcohols and carbon monoxide has been achieved by means of a Rh-catalysed oxidative carbonylation reaction that uses Oxone as a stoichiometric oxidant. In-depth studies on the reaction mechanism shed light on the intimate role of Oxone in the catalytic cycle.
URIhttp://hdl.handle.net/10261/155816
Identifiersdoi: 10.1039/C6CC09133D
e-issn: 1364-548X
issn: 1359-7345
Appears in Collections:(ISQCH) Artículos
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