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Título: | Recent advances on asymmetric nitroso aldol reaction |
Autor: | Merino, Pedro CSIC ORCID ; Tejero, Tomás CSIC ORCID; Delso, J. Ignacio CSIC ORCID; Matute, Rosa | Palabras clave: | Aminoxylation Asymmetric nitroso aldol α-amino carbonyls Hydroxyamination Organocatalysts α-hydroxy carbonyls |
Fecha de publicación: | 2016 | Editor: | Thieme | Citación: | Synthesis 48(05): 653-676 (2016) | Resumen: | The reaction of aromatic nitroso derivatives with enolizable carbonyl compounds (nitroso aldol reaction) to give either α-hydroxyamino or α-aminoxy carbonyl compounds is an important synthetic method. This review illustrates the recent advances in rendering the process regio- and enantioselective as well as catalytic. By employing metal and organic catalysts a range of α-amino (α-oxyamination) and α-hydroxy (α-aminoxylation) carbonyl derivatives can be generated with total regioselectivity and high levels of enantiomeric excess. | Versión del editor: | https://doi.org/10.1055/s-0035-1561505 | URI: | http://hdl.handle.net/10261/155774 | DOI: | 10.1055/s-0035-1561505 | Identificadores: | doi: 10.1055/s-0035-1561505 e-issn: 1437-210X issn: 0039-7881 |
Aparece en las colecciones: | (ISQCH) Artículos |
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NitrosoAldol.pdf | 854,05 kB | Adobe PDF | Visualizar/Abrir |
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