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Title

Recent advances on asymmetric nitroso aldol reaction

AuthorsMerino, Pedro ; Tejero, Tomás ; Delso, J. Ignacio; Matute, Rosa
KeywordsAminoxylation
Asymmetric nitroso aldol
α-amino carbonyls
Hydroxyamination
Organocatalysts
α-hydroxy carbonyls
Issue Date2016
PublisherThieme
CitationSynthesis 48(05): 653-676 (2016)
AbstractThe reaction of aromatic nitroso derivatives with enolizable carbonyl compounds (nitroso aldol reaction) to give either α-hydroxyamino or α-aminoxy carbonyl compounds is an important synthetic method. This review illustrates the recent advances in rendering the process regio- and enantioselective as well as catalytic. By employing metal and organic catalysts a range of α-amino (α-oxyamination) and α-hydroxy (α-aminoxylation) carbonyl derivatives can be generated with total regioselectivity and high levels of enantiomeric excess.
Publisher version (URL)https://doi.org/10.1055/s-0035-1561505
URIhttp://hdl.handle.net/10261/155774
DOI10.1055/s-0035-1561505
Identifiersdoi: 10.1055/s-0035-1561505
e-issn: 1437-210X
issn: 0039-7881
Appears in Collections:(ISQCH) Artículos
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