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Chemical polymerization of polyaniline and polypyrrole by phosphomolybdic acid : In situ formation of hybrid organic-inorganic materials

AuthorsGómez-Romero, P. CSIC ORCID ; Casañ Pastor, Nieves CSIC ORCID; Lira-Cantú, Mónica CSIC ORCID
KeywordsHybrid organic-inorganic compounds
Conducting polymers
Issue DateNov-1997
CitationSolid State Ionics 101-103(2): 875-880 (1997)
AbstractThe oxidative polymerization of aniline or pyrrole by phosphomolybdic acid (H3PMo12O40) is described. These reactions take place in the absence of other anions and result in the incorporation of the photoactive and electroactive PMo12O403− anion into the lattice of the polymer. The resulting hybrid materials present the good conductivity and polymeric nature of the matrix plus the added electroactivity of the inorganic cluster, which is anchored in the polymer and not exchanged upon reduction. The hybrids can work as electrodes harnessing the electrochemical properties of the polyoxometalic clusters
DescriptionInternational Symposium on the Reactivity of Solids.
Publisher version (URL)http://dx.doi.org/10.1016/S0167-2738(97)00222-1
Appears in Collections:(ICMAB) Artículos
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