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Título

Electrochemical and Chemical Syntheses of the Hybrid Organic-Inorganic Electroactive Material formed by Phosphomolybdate and Polyaniline. Application as Cation-Insertion Electrodes

AutorLira-Cantú, Mónica ; Gómez-Romero, P.
Palabras claveCation-Insertion Electrodes
Electrochemical and Chemical Syntheses
Fecha de publicación18-feb-1998
EditorAmerican Chemical Society
CitaciónChemistry of Materials 10(3): 698-704 (1998)
ResumenWe report a hybrid organic-inorganic electroactive material composed of a conducting polyaniline matrix and the phosphomolybdate anion ([PMo12O40]3-) as the active inorganic component. The material can be prepared electrochemically as thin films or chemically in the bulk, in the absence of other competing anions. The phosphomolybdate anion is anchored within the polymer matrix and not exchanged upon reduction. The material presents good conductivity and electroactivity, and it represents an example of electrodes that can take advantage of the electroactivity of zero-dimensional molecular species. A preliminary analysis of the material as a cathode in reversible lithium batteries is discussed
Versión del editorhttp://dx.doi.org/10.1021/cm970107u
URIhttp://hdl.handle.net/10261/15493
DOI10.1021/cm970107u
ISSN0897-4756
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