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dc.contributor.authorLuquin, Asunción-
dc.contributor.authorCastillo, Noelia-
dc.contributor.authorCerrada, Elena-
dc.contributor.authorMerchán Álvarez, Francisco-
dc.contributor.authorGarrido, Julián J.-
dc.contributor.authorLaguna, Mariano-
dc.date.accessioned2017-09-08T12:10:07Z-
dc.date.available2017-09-08T12:10:07Z-
dc.date.issued2016-
dc.identifierdoi: 10.1002/ejoc.201501354-
dc.identifiere-issn: 1099-0690-
dc.identifierissn: 1434-193X-
dc.identifier.citationEuropean Journal of Organic Chemistry 2016(4): 789-798 (2016)-
dc.identifier.urihttp://hdl.handle.net/10261/154922-
dc.description.abstractPdII complexes with PPh(o-C6H4SMe)2 acting as a pincer ligand in an S,S′,P- or S,P-coordination mode have been synthesized. The complexes include [PdCl2{PPh(o-C6H4SMe)2}] (1), [Pd(Me)Cl{PPh(o-C6H4SMe)2}] (2), and [Pd(X){PPh(o-C6H4SMe)2}]A [A = CF3SO3, X = Cl (3); A = CF3SO3, Me (4); A = PF6, X = Me (5)]. Insertion of CO into the Pd–Me bond of these complexes leads to [Pd(COMe)Cl{PPh(o-C6H4SMe)2}] (6) and [Pd(COMe){PPh(o-C6H4SMe)2}]A [A = CF3SO3 (7); A = PF6 (8)]. Some of these complexes are good Mizoroki–Heck catalysts (for the reactions between iodobenzene and methyl acrylate or styrene). The most active catalyst was found to be [Pd(Me)Cl{PPh(o-C6H4SMe)2}] (2). This catalyst could be retained on a silica gel column, recovered, and reused several times without losing activity.-
dc.description.sponsorshipAuthors thank the Gobierno de Aragon (Spain) for financial support (Applied Organometallic Chemistry, E101 group).-
dc.publisherWiley-VCH-
dc.rightsclosedAccess-
dc.subjectHomogeneous catalysis-
dc.subjectLigand design-
dc.subjectPincer ligands-
dc.titlePalladium(II) complexes of the hemilabile pincer ligand PPh(o-C6H4SMe)2 as highly active and recyclable ­Mizoroki–Heck catalysts-
dc.typeartículo-
dc.identifier.doi10.1002/ejoc.201501354-
dc.date.updated2017-09-08T12:10:08Z-
dc.description.versionPeer Reviewed-
dc.language.rfc3066eng-
dc.contributor.funderGobierno de Aragón-
dc.relation.csic-
dc.identifier.funderhttp://dx.doi.org/10.13039/501100010067es_ES
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