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http://hdl.handle.net/10261/154908
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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Troyano, Javier | - |
dc.contributor.author | Perles, Josefina | - |
dc.contributor.author | Amo-Ochoa, Pilar | - |
dc.contributor.author | Martínez, José I. | - |
dc.contributor.author | Gimeno, M. Concepción | - |
dc.contributor.author | Fernández-Moreira, Vanesa | - |
dc.contributor.author | Zamora, Félix | - |
dc.contributor.author | Delgado, Salomé | - |
dc.date.accessioned | 2017-09-08T10:42:06Z | - |
dc.date.available | 2017-09-08T10:42:06Z | - |
dc.date.issued | 2016 | - |
dc.identifier | doi: 10.1002/chem.201603675 | - |
dc.identifier | e-issn: 1521-3765 | - |
dc.identifier | e-issn: 0947-6539 | - |
dc.identifier.citation | Chemistry - A European Journal 22(50): 18027-18035 (2016) | - |
dc.identifier.uri | http://hdl.handle.net/10261/154908 | - |
dc.description | PMCID: PMC5166966. | - |
dc.description.abstract | Solvothermal reactions between copper(I) halides and 4-mercaptophenol give rise to the formation of three coordination polymers with general formula [Cu3X(HT)2]n (X=Cl, 1; Br, 2; and I, 3). The structures of these coordination polymers have been determined by X-ray diffraction at both room- and low temperature (110 K), showing a general shortening in Cu−S, Cu−X and Cu−Cu bond lengths at low temperatures. 1 and 2 are isostructural, consisting of layers in which the halogen ligands act as μ3-bridges joining two Cu1 and one Cu2 atoms whereas in 3 the iodine ligands is as μ4-mode but the layers are quasi-isostructural with 1 or 2. These compounds show a reversible thermochromic luminescence, with strong orange emission for 1 and 2, but weaker for 3 at room temperature, whereas upon cooling at 77 K 1 and 2 show stronger yellow emission, and 3 displays stronger green emission. DFT calculations have been used to rationalize these observations. These results suggest a high potential for this novel and promising stimuli-responsive materials. | - |
dc.description.sponsorship | This work was supported by MICINN (MAT2013-46753-C2-1-P and MAT2016-77608-C3-1-P). J.I.M. acknowledges funding fromthe ERC-Synergy Program (Grant ERC-2013-SYG-610256 NANO-COSMOS) and computing resources from CTI-CSIC. | - |
dc.publisher | Wiley-VCH | - |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2016-77608-C3-1-P | - |
dc.relation | info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2013-46753-C2-1-P | - |
dc.relation | info:eu-repo/grantAgreement/EC/FP7/610256 | - |
dc.relation.isversionof | Postprint | - |
dc.rights | openAccess | - |
dc.subject | multifunctional materials | - |
dc.subject | Coordination polymers | - |
dc.subject | Luminescent materials | - |
dc.subject | Stimuli-responsive materials | - |
dc.subject | Thermochromic coordination polymers | - |
dc.title | Luminescent thermochromism of 2D coordination polymers based on copper(I) halides with 4-hydroxythiophenol | - |
dc.type | artículo | - |
dc.identifier.doi | 10.1002/chem.201603675 | - |
dc.relation.publisherversion | https://doi.org/10.1002/chem.201603675 | - |
dc.date.updated | 2017-09-08T10:42:07Z | - |
dc.description.version | Peer Reviewed | - |
dc.language.rfc3066 | eng | - |
dc.contributor.funder | Consejo Superior de Investigaciones Científicas (España) | - |
dc.contributor.funder | European Research Council | - |
dc.contributor.funder | Ministerio de Ciencia e Innovación (España) | - |
dc.contributor.funder | Ministerio de Economía y Competitividad (España) | - |
dc.relation.csic | Sí | - |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003339 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100004837 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003329 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100000781 | es_ES |
dc.identifier.pmid | 27809369 | - |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.grantfulltext | open | - |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | With Fulltext | - |
Aparece en las colecciones: | (ICMM) Artículos (ISQCH) Artículos |
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Fichero | Descripción | Tamaño | Formato | |
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HydroxythiophenolPMC.pdf | 2,3 MB | Adobe PDF | Visualizar/Abrir |
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