English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/154860
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:


Detangling catalyst modification reactions from the oxygen evolution reaction by online mass spectrometry

AuthorsAbril, Paula ; Río, M. Pilar del ; Tejel, Cristina ; Verhoeven, Tiny W. G. M.; Hans Niemantsverdriet, J. W.; Ham, Cornelis J. M. van der; Kottrup, Konstantin G.; Hetterscheid, Dennis G. H.
Issue Date2016
PublisherAmerican Chemical Society
CitationACS Catalysis 6(11): 7872-7875 (2016)
AbstractHere we showcase the synthesis and catalytic response of the anionic iridium(III) complex [IrCl(pic)(MeOH)] ([1], pic = picolinate) toward the evolution of oxygen. Online electrochemical mass spectrometry experiments illustrate that an initial burst of CO due to catalyst degradation is expelled before the oxygen evolution reaction commences. Electrochemical features and XPS analysis illustrate the presence of iridium oxide, which is the true active species.
Identifiersdoi: 10.1021/acscatal.6b02800
e-issn: 2155-5435
Appears in Collections:(ISQCH) Artículos
Files in This Item:
File Description SizeFormat 
accesoRestringido.pdf15,38 kBAdobe PDFThumbnail
Show full item record
Review this work

Related articles:

WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.