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Title

Detangling catalyst modification reactions from the oxygen evolution reaction by online mass spectrometry

AuthorsAbril, Paula ; Río, M. Pilar del ; Tejel, Cristina ; Verhoeven, Tiny W. G. M.; Hans Niemantsverdriet, J. W.; Ham, Cornelis J. M. van der; Kottrup, Konstantin G.; Hetterscheid, Dennis G. H.
KeywordsEvolution
Oxygen
Reaction
Issue Date2016
PublisherAmerican Chemical Society
CitationACS Catalysis 6(11): 7872-7875 (2016)
AbstractHere we showcase the synthesis and catalytic response of the anionic iridium(III) complex [IrCl(pic)(MeOH)] ([1], pic = picolinate) toward the evolution of oxygen. Online electrochemical mass spectrometry experiments illustrate that an initial burst of CO due to catalyst degradation is expelled before the oxygen evolution reaction commences. Electrochemical features and XPS analysis illustrate the presence of iridium oxide, which is the true active species.
URIhttp://hdl.handle.net/10261/154860
DOI10.1021/acscatal.6b02800
Identifiersdoi: 10.1021/acscatal.6b02800
e-issn: 2155-5435
Appears in Collections:(ISQCH) Artículos
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